Theory of linear sweep voltammetry with diffuse charge: Unsupported electrolytes, thin films, and leaky membranes

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Theory of linear sweep voltammetry with diffuse charge: Unsupported electrolytes, thin films, and leaky membranes.

Linear sweep and cyclic voltammetry techniques are important tools for electrochemists and have a variety of applications in engineering. Voltammetry has classically been treated with the Randles-Sevcik equation, which assumes an electroneutral supported electrolyte. In this paper, we provide a comprehensive mathematical theory of voltammetry in electrochemical cells with unsupported electrolyt...

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ژورنال

عنوان ژورنال: Physical Review E

سال: 2017

ISSN: 2470-0045,2470-0053

DOI: 10.1103/physreve.95.033303